Tuning Polyethylene Molecular Weight Distributions Using Catalyst Support Composition
نویسندگان
چکیده
Bimodal polyethylene is generated from a single immobilized catalyst on support under set of reaction conditions without introducing chain transfer agents. Using rac-ethylenebis(1-indenyl)zirconium dichloride [(EBI)ZrCl2] nickel-containing layered double hydroxide (LDH) produces two distinct molecular weight distributions. The ratio these fractions can be tuned by varying the LDH as well changing conditions.
منابع مشابه
Synthesis of high molecular weight polyethylene using FI catalyst
A FI Zr-based catalyst of bis[N-(3,5-dicumylsalicylidene)-2′,6′diisopropylanilinato]zirconium(IV) dichloride was prepared and used for polymerization of ethylene. The effects of reaction conditions on the polymerization were examined in detail. The increase in ethylene pressure and rise in polymerization temperature up to 35 oC were favorable for catalyst/MAO to raise the catalytic activity as...
متن کاملsynthesis of high molecular weight polyethylene using fi catalyst
a fi zr-based catalyst of bis[n-(3,5-dicumylsalicylidene)-2′,6′diisopropylanilinato]zirconium(iv) dichloride was prepared and used for polymerization of ethylene. the effects of reaction conditions on the polymerization were examined in detail. the increase in ethylene pressure and rise in polymerization temperature up to 35 oc were favorable for catalyst/mao to raise the catalytic activity as...
متن کاملPreparation of Ultra High Molecular Weight Polyethylene Using Ziegler-Natta Catalyst System: Optimization of Parameters by Response Surface Methodology
متن کامل
Support Weight Enumerators and Coset Weight Distributions of Isodual Codes
In this paper various methods for computing the support weight enumerators of binary, linear, even, isodual codes are described. It is shown that there exist relationships between support weight enumerators and coset weight distributions of a code that can be used to compute partial information about one set of these code invariants from the other. The support weight enumerators and complete co...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Macromolecules
سال: 2022
ISSN: ['0024-9297', '1520-5835']
DOI: https://doi.org/10.1021/acs.macromol.1c02604